John Rakovan
Associate Professor

Ph.D. (1996) SUNY @ Stony Brook
126 Shideler Hall
513-529-3245
rakovajf@muohio.edu

My research interests involve the integration of low temperature geochemistry and mineralogy in the study of crystal surfaces and water-rock interactions found in natural systems. In particular, I am interested in processes such as crystal growth, metal sorption, trace element partitioning and other surface mediated reactions. I am also concerned with the structural response of minerals to substituent elements, especially lanthanides and actinides in apatite group minerals.

Possible thesis/dissertation topics:

Surface structural controls on trace element incorporation into minerals during growth.

Crystal chemistry of the lanthanides and actinides in apatite group minerals.

Mechanics and kinetics of crystal growth from aqueous solutions.

Trace metal cycling in the lakes of the dry valleys, Antarctica.

Current/recent graduate student research:

Olaf Borkiewicz (Ph.D. in progress) The role of precursor formation on actinide sequestration and retention in low temperature growth of apatite.

Yun Luo (Ph.D. in progress) Crystal Chemistry of U and Th in apatite.

Frederick Partey (M.S. 2004) Origin of fluorine and fluorite mineralization in the Rio Grande Rift system.

Carrie Wright (M.S. 2003) Spectroscopic investigation of the coupling of REEs and defect centers in fluorite and the origin of color.

Art Losey (M.S. 2002) Structural variation in the lithiophilite-tryphilite series and characterization of light element (Li, Be, and B) mineral standards.

Selected publications:

Krekeler, K., Hammerly, E., Rakovan, J. and Guggenheim, S. (2005) Microscopy Studies of the Palygorskite to Smectite Transformation. Clay and Clay Minerals, 53, 92-99.

Losey, A., Rakovan, J., Hughes, J.M., Francis, C.A. and Dyar, M.D. (2004) Structural variation in the lithiophilite-tryphylite series and other olivine-group structures. Canadian Mineralogist, 42, 1105-1115.

Meng, Y., Newville, M., Sutton, S., Rakovan, J. and Mao, H.K. (2003) Fe and Ni impurities in synthetic diamond. American Mineralogist, 88, 1555-1559.

Rakovan, J. (2002) Growth and surface structure of apatite. In: Phosphates: Geochemical, Geobiological and materials importance, Kohn, M., Rakovan, J. and Hughes, J. (eds): Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Washington, D.C.

Rakovan, J., Reeder, R.J., Elzinga, E.J., Cherniak, D., Tait, C.D. and Morris, D.E. (2002) Characterization of U(VI) in the apatite structure by X-ray absorption and spectroscopy: Environmental Science and Technology, 36, 3114-3117.

Selected grants:

National Science Foundation 2004 (with Hughes and Cahill, C.)
Crystal chemistry of U, Th and other Radionuclides in Apatite: Environmental and Geochemical Implications.

National Science Foundation 2003 (with Dong, Pacey and Edelmann)
Acquisition of a Scanning Electron Microscope for Nanotechnology Investigations.

National Science Foundation 2000 (with Hughes)
Acquisition of a CCD-detector Single Crystal X-ray Diffractometer.

Teaching Interests:

GLG 111 - The Dynamic Earth - click here for a complete description.
GLG 201 - Mineralogy - click here for a complete description.
GLG 280D - Gems & Gem Mineral Formation - click here for a complete description.
GLG 430/530 - Mineral-Water Interface Geochemistry - click here for a complete description.
GLG 432/532 - Clay and Clay Mineralogy - click here for a complete description.

For more information please visit Dr. Rakovan's personal web page.

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